Recently reported crystalline isothiazole carbenes: Myth or reality

DOI: 10.1002/anie.200702272

Source and publish data:

Angewandte Chemie - International Edition p. 6922 - 6925 (2007)

Update date:2022-09-26

Topics:

Authors:

DeHope, Alan

Lavallo, Vincent

Donnadieu, Bruno

Schoeller, Wolfgang W.

Bertrand, Guy

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/anie.200702272

(Chemical Equation Presented) Singlet carbenes are not always stable: Isothiazole carbenes, recently reported as crystalline solids, cannot even be observed at room temperature; they rearrange into their 2-imino-2H-thiete isomers with an energy barrier of

Full text of DOI:10.1002/anie.200702272

Products guided by the article

Product name:C₂₅H₂₄N₂OS

Cas No:951287-41-5

R&D Labs maybe for 951287-41-5

N&R INDUSTRIES,INC

Contact:Tel:+86-29-88764861 Fax:+86-29-88764861

Address:Rm#2107, Block A, Epin Meidao Building, Gaoxin Rd, Hi-Tech Zone, Xi’an, China
Buffett (China) Holding Co.,Ltd

Contact:4006570891

Address:
Tianjin Hedong Red Cliff Chemical Reagent Factory

Contact:+86-022-84780548

Address:Li Ming Zhuang Gong Ye Yuan,Dongli District,Tianjin,China
Rizhao Lanxing Chemical Indusrial Co.,Ltd

Contact:86-633-2616708

Address:NO.15 West road Shenglan, Lanshan district, Rizhao City
Nanjing HuiBaiShi Biotechnology Co.,Ltd.

Contact:+86 (25)58745219

Address:No.606 Ningliu Road,LiuHe District.

Relevant to this article

A VICARIOUS AROMATIC SUBSTITUTION APPROACH TO AKLAVINONE FROM CHRYSAZIN

Doi:10.1016/S0040-4039(01)80031-9
(1984)
5-Amino-2-phenyl[1,2,3]triazolo[1,2-a][1,2,4]benzotriazin-1-one: A versatile scaffold to obtain potent and selective A₃ adenosine receptor antagonists

Doi:10.1021/jm0708376
(2007)
Insertion of Carbon Dioxide, of CO2-like Molecules, and of Other Unsaturated Compounds into the Platinum-Nitrogen Bond of

Doi:10.1039/DT9850000163
(1985)
Asymmetric Michael Additions via SAMP-/RAMP-Hydrazones. Enantioselective Synthesis of 2-Substituted 4-Oxosulfones

Doi:10.1016/S0040-4020(01)80538-X
(1993)
An efficient and scalable synthesis of substituted phenanthrenequinones by intramolecular Friedel-Crafts reaction of imidazolies

Doi:10.1021/ol071261h
(2007)
Studies on the Chemistry of Thienoanellated O,N- and S,N-Containing Heterocycles, X: Synthesis of 2-Substituted Thieno-Diltiazem Derivatives

Doi:10.1007/BF00807431
(1995)

Article Doi