Activation of Benzylic Amines Towards Regioselective Metallation by Borane Complex Formation

DOI: 10.1016/0040-4039(95)01797-L

Source and publish data:

Tetrahedron Letters p. 8697 - 8700 (1995)

Update date:2022-07-30

Topics:

Authors:

Ebden, Mark R.

Simpkins, Nigel S.

Fox, David N. A.

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Article abstract of DOI:10.1016/0040-4039(95)01797-L

Formation of borane complexes of N,N-dimethylbenzylamine 4 and N-methyltetrahydroisoquinoline 1 facilitates regioselective metallation of these systems using BuLi, giving benzylic anions which react with a range of electrophiles.

Full text of DOI:10.1016/0040-4039(95)01797-L

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