Tetrahedron Letters p. 5719 - 5722 (1984)
Update date:2022-08-04
Topics:
Akermark, Bjoern
Nystroem, Jan-E.
Rein, Tobias
Baeckvall, Jan-E.
Helquist, Paul
Aslanian, Robert
The palladium(II)-catalyzed chloroacetoxylation of 1,3-dienes is employed to prepare 1-chloro-4-acetoxy-2-alkenes which are then transformed into 1-phosphoryl- or 1-sulfonyl-4-acetoxy-2-alkenes respectively.Elimination of acetate is promoted by palladium(
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