Unprecedented Higher Stability of E- than Z-Olefin Complexes of Platinum(II). Molecular Structures of the η3-Methallyl(triphenylphosphine)(Z- and E-but-2-ene)platinum(II) Cation

DOI: 10.1039/c39840001520

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1520 - 1522 (1984)

Update date:2022-08-05

Topics:

Authors:

Miki, Kunio

Yamatoya, Kazuhiko

Kasai, Nobutami

Kurosawa, Hideo

Emoto, Misuhiro

Urabe, Akira

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39840001520

The C=C bond of Z-but-2-ene in one of the title complexes lies almost in the co-ordination plane, while that of the corresponding E-but-2-ene complex, which unprecedentedly is more stable in solution than the former, forms an angle of 67 deg with the plan

Full text of DOI:10.1039/c39840001520

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:{(η3-CH2CMeCH2)Pt(PPh2)((Z)-MeCH=CHMe)}PF6

Cas No:95340-41-3

R&D Labs maybe for 95340-41-3

Wuxi Pharma-Trading Import & Export Co.,Ltd.

Contact:+86-510-82304590 82716390

Address:Room 523,Youzu Alliance Building,No.88 Renmin Zhonglu,Wuxi,Jiangsu,China
Shijiazhuang Haitian Amino Acid Co., Ltd.

Contact:+86-311-88908111

Address:Shijiazhuang Hebei province,China
Changsha Botaniex Inc.

Contact:(86) 731 88718666

Address:Room 1222, Unit 4, Building B, Shangcheng, No.47, Kaiyuan East Road.
ALPHA PHARMACEUTICAL CO，LTD JIANGSU

Contact:+86-527-84829968,+86-527-84829998

Address:suqian city
Angelisun(Chongqing) Pharmaceutical Co., LTD.

Contact:+86-23-68030926-816

Address:D1-7 Tech & Entrepreneurs Park, Kecheng Road, Erlang Hi-Tech Areas, Chongqing, China

Relevant to this article

Synthesis and bioactivity of a novel series of 3,6-disubstituted 1,2,4-triazolo[3,4-b]-1,3,4-thiadiazoles

Doi:10.1016/j.cclet.2009.11.008
(2010)
Aluminum Dichloride and Dibromide. Preparation, Spectroscopic (Including Matrix Isolation) Study, Reactions, and Role (Together with Alkyl(aryl)aluminum Monohalides) in the Preparation of Organoaluminum Compounds

Doi:10.1021/ja00218a037
(1988)
Doi:10.1021/jo01044a003
(1963)
Mechanism of methyl esterification of carboxylic acids by trimethylsilyldiazomethane

Doi:10.1002/anie.200702131
(2007)
Isothiazoles as active-site inhibitors of HCV NS5B polymerase

Doi:10.1016/j.bmcl.2006.10.002
(2007)
Generation of arynes triggered by sulfoxidemetal exchange reaction of ortho-sulfinylaryl triflates

Doi:10.1246/cl.130899
(2014)

Article Doi