Unprecedented Higher Stability of E- than Z-Olefin Complexes of Platinum(II). Molecular Structures of the η3-Methallyl(triphenylphosphine)(Z- and E-but-2-ene)platinum(II) Cation

DOI: 10.1039/c39840001520

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1520 - 1522 (1984)

Update date:2022-08-05

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Authors:

Miki, Kunio

Yamatoya, Kazuhiko

Kasai, Nobutami

Kurosawa, Hideo

Emoto, Misuhiro

Urabe, Akira

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Article abstract of DOI:10.1039/c39840001520

The C=C bond of Z-but-2-ene in one of the title complexes lies almost in the co-ordination plane, while that of the corresponding E-but-2-ene complex, which unprecedentedly is more stable in solution than the former, forms an angle of 67 deg with the plan

Full text of DOI:10.1039/c39840001520

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