Chemistry Letters p. 1803 - 1806 (1984)
Update date:2022-08-02
Topics:
Tsuge, Otohiko
Kanemasa, Shuji
Nagahama, Hideki
Tanaka, Junji
Desilylation of α-alkoxysilanes offers the convenient generation of carbinyl carbanions which react with a variety of carbonyl compounds giving mono-protected 1,2-diols of unsymmetrical type.Dehydration of these unsymmetrical diols leads to the regioselective formation of methyl ketones.
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