Journal of Organometallic Chemistry p. 63 - 86 (1985)
Update date:2022-08-05
Topics:
Benn, R.
Buessemeier, B.
Holle, S.
Jolly, P. W.
Mynott, R.
et all.
Butadiene and methylsubstituted 1,3-dienes react with zerovalent-nickel-ligand complexes in a stoichiometric manner to give octadiendylnickel-ligand complexes.The structure, rearrangement and reactions with CO and P-donor ligands of these species have been studied with the help of 1H and 13C NMR spectroscopy.The results provide an insight into the mechanism of the nickel-catalyesd cyclodimerization of 1,3-dienes.
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