Journal of Organic Chemistry p. 1681 - 1688 (1985)
Update date:2022-08-03
Topics:
Machida, Minoru
Oda, Kazuaki
Yoshida, Eiichi
Kanaoka, Yuichi
General photochemical behavior of cyclic thioimides, nitrogen-thiocarbonyl systems, was studied.The dithioimides were inert to the Norrish type I and II reactions in contrast to the behavior of their oxygen analogues (imides) and nitrogen-lacking counterparts (thiones).However, various aliphatic and aromatic di- and monothioimides underwent intermolecularly efficient photocycloaddition with olefins to afford the imide-thietanes in good yields.
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