Tetrahedron p. 4527 - 4534 (1984)
Update date:2022-08-04
Topics:
Florio, Saverio
Epifani, Erbana
Ingrosso, Giovanni
The title benzothiazoles 1 react with allylic Grignard reagents affording 2-allylbenzothiazoles 5, 2,2-diallylbenzothiazolines 6 and N-triallylmethyl-o-aminobenzenethiols as disulphides 7 depending upon the experimental conditions.The reaction is considerably influenced by the solvent used and the nature of the allylic Grignard.A possible mechanism for the formation of compounds 5, 6 and 7 is reported.
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