Silicon in Synthesis. 21. Reagents for Thiophenyl-Functionalized Cyclopentenone Annulations and the Total Synthesis of (+/-)-Hirsutene

DOI: 10.1021/jo00210a013

Source and publish data:

Journal of Organic Chemistry p. 1621 - 1626 (1985)

Update date:2022-08-05

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Authors:

Magnus, Philip

Quagliato, Dominick

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Article abstract of DOI:10.1021/jo00210a013

1-(Trimethylsilyl)-1-(phenylthio)ethylene (1) reacts with cyclic α,β-unsaturated acid chlorides to give β-mercaptophenyl-substituted cyclopentenones, whereas 1-(trimethylsilyl)-2-(phenylthio)ethylene (2) under similar conditions results in thiophenyl migr

Full text of DOI:10.1021/jo00210a013

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