Silicon in Synthesis. 21. Reagents for Thiophenyl-Functionalized Cyclopentenone Annulations and the Total Synthesis of (+/-)-Hirsutene

DOI: 10.1021/jo00210a013

Source and publish data:

Journal of Organic Chemistry p. 1621 - 1626 (1985)

Update date:2022-08-05

Topics:

Authors:

Magnus, Philip

Quagliato, Dominick

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00210a013

1-(Trimethylsilyl)-1-(phenylthio)ethylene (1) reacts with cyclic α,β-unsaturated acid chlorides to give β-mercaptophenyl-substituted cyclopentenones, whereas 1-(trimethylsilyl)-2-(phenylthio)ethylene (2) under similar conditions results in thiophenyl migr

Full text of DOI:10.1021/jo00210a013

Products guided by the article

Product name:9-methyl-4-(phenylthio)cis-bicyclo<4.3.0>non-3-en-2-one

Cas No:95841-52-4

R&D Labs maybe for 95841-52-4

GenicBio Limited

Contact:+86-(0)21-3770 9035

Address:Room 301, Building 2, Meijiabang Road 1508, Shanghai China
Jiaxing Anrui Material Technology Co., Ltd.

Contact:86-573-82651652 13305832579

Address:Room 407, Technology Building, 1369 Chennan Road, Jiaxing City, Zhejiang, China
Tianjin Ji Ping Jia Chemical Co., Ltd.

Contact:18622448868

Address:tianjin
Dalian Join King Biochemical Tech. Co., Ltd.

Contact:0411 39216206

Address:814 First State Blvd
Zhejiang Sanmei Chemical Industry Co., Ltd

Contact:86-579-87633213

Address:Huchu Industrial Zone, Qingnian Rd., Wuyi County, Zhejiang Prov., China.

Relevant to this article

The synthesis of some new derivatives derived from 1,2,3,4- tetrahydrocyclohepteno[4,5]thieno-[2,3-d]pyrimidine

Doi:10.1080/10426500600865293
(2007)
Enantioselective construction of quaternary stereogenic carbons by the Lewis base catalyzed additions of silyl ketene imines to aldehydes

Doi:10.1021/ja077134y
(2007)
Bone targeting prodrugs based on peptide dendrimers, synthesis and hydroxyapatite binding in vitro

Doi:10.2174/157017809788489981
(2009)
Studies on peptides. CXXVI. Synthesis of the protected tetracosapeptide corresponding to positions 30-53 of mouse epidermal growth factor (EGF)

Doi:10.1248/cpb.33.173
(1985)
Doi:10.1139/v63-143
(1963)
Air-assisted addition of grignard reagents to olefins. A simple protocol for a three-component coupling process yielding alcohols

Doi:10.1021/ja055732b
(2005)

Article Doi