Silicon in Synthesis. 21. Reagents for Thiophenyl-Functionalized Cyclopentenone Annulations and the Total Synthesis of (+/-)-Hirsutene

DOI: 10.1021/jo00210a013

Source and publish data:

Journal of Organic Chemistry p. 1621 - 1626 (1985)

Update date:2022-08-05

Topics:

Authors:

Magnus, Philip

Quagliato, Dominick

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00210a013

1-(Trimethylsilyl)-1-(phenylthio)ethylene (1) reacts with cyclic α,β-unsaturated acid chlorides to give β-mercaptophenyl-substituted cyclopentenones, whereas 1-(trimethylsilyl)-2-(phenylthio)ethylene (2) under similar conditions results in thiophenyl migr

Full text of DOI:10.1021/jo00210a013

Products guided by the article

Product name:9-methyl-4-(phenylthio)cis-bicyclo<4.3.0>non-3-en-2-one

Cas No:95841-52-4

R&D Labs maybe for 95841-52-4

SHANGHAI RC CHEMICALS CO.,LTD.

website:http://www.rcc.net.cn

Contact:+86-21-50322175

Address:Rm1415 Yinqiao Masion No.58 Jinxin Road Pudong Shanghai China
Chemvon Biotechnology Co. Ltd.

website:http://www.chemvon.com

Contact:86-21-58550039;86-21-31268550-8004

Address:Suite B-10#, 6999 Chuansha Road, Pudong District, Shanghai 201202, China
Ring Specialty Chemicals Inc.

website:http://www.ringchemicals.com/

Contact:+1-416-493-6870

Address:Toronto, Canada
Nantong LiKai Chemical Co.,Ltd

Contact:+86-513-89068669

Address:Jincheng Science Park
Tangshan Moneide Trading Co., Ltd.

Contact:+86-315-8309571

Address:2-7-420 Jidong Building Materials Commercial Center, Tangshan, Hebei, 064000 China

Relevant to this article

The synthesis of some new derivatives derived from 1,2,3,4- tetrahydrocyclohepteno[4,5]thieno-[2,3-d]pyrimidine

Doi:10.1080/10426500600865293
(2007)
Enantioselective construction of quaternary stereogenic carbons by the Lewis base catalyzed additions of silyl ketene imines to aldehydes

Doi:10.1021/ja077134y
(2007)
Bone targeting prodrugs based on peptide dendrimers, synthesis and hydroxyapatite binding in vitro

Doi:10.2174/157017809788489981
(2009)
Studies on peptides. CXXVI. Synthesis of the protected tetracosapeptide corresponding to positions 30-53 of mouse epidermal growth factor (EGF)

Doi:10.1248/cpb.33.173
(1985)
Doi:10.1139/v63-143
(1963)
Air-assisted addition of grignard reagents to olefins. A simple protocol for a three-component coupling process yielding alcohols

Doi:10.1021/ja055732b
(2005)

Article Doi