Stereochemistry of P-N Bond Cleavage. First Crystal and Structural Assignment in Cyclic Phosphoramidofluoridates

DOI: 10.1021/jo00211a005

Source and publish data:

Journal of Organic Chemistry p. 1815 - 1818 (1985)

Update date:2022-08-04

Topics:

Authors:

Misiura, Konrad

Silverton, James V.

Stec, Wojciech J.

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Article abstract of DOI:10.1021/jo00211a005

Diastereomers of 2-(N-ethyleneimino)-2-oxo-3-(α-methylbenzyl)-1,3,2-oxazaphosphorinane have been found to react with poly(hydrogen fluoride-pyridine).Displacement of the ethyleneimino ligand by the fluoride ion is fully stereospecific and occurs with inve

Full text of DOI:10.1021/jo00211a005

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