Stereochemistry of P-N Bond Cleavage. First Crystal and Structural Assignment in Cyclic Phosphoramidofluoridates

DOI: 10.1021/jo00211a005

Source and publish data:

Journal of Organic Chemistry p. 1815 - 1818 (1985)

Update date:2022-08-04

Topics:

Authors:

Misiura, Konrad

Silverton, James V.

Stec, Wojciech J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00211a005

Diastereomers of 2-(N-ethyleneimino)-2-oxo-3-(α-methylbenzyl)-1,3,2-oxazaphosphorinane have been found to react with poly(hydrogen fluoride-pyridine).Displacement of the ethyleneimino ligand by the fluoride ion is fully stereospecific and occurs with inve

Full text of DOI:10.1021/jo00211a005

Products guided by the article

Product name:2(R)-fluoro-2-oxo-3-<3(S)-α-methylbenzyl>-1,3,2-oxazaphosphorinane

Cas No:95999-20-5

R&D Labs maybe for 95999-20-5

Shanghai PuYi Chem-Tech Co.,Ltd.

Contact:+86-21-57687505-227

Address:3 Floor, Building 11, No 201 MinYi Road, Songjiang District, Shanghai 201612, China
Suzhou Time-chem Technologies Co., Ltd.

Contact:0512-63983931/68086856

Address:No. 1326 of Binhe Road, New District, Suzhou, Jiangsu, P. R. China
Changsha Nutritopper Bio Technology Co.,Ltd.

Contact:+86-731-87803543

Address:East 1st Street, Baima Road, Ningxiang County
Shandong Yuanli Science and Technology Co., Ltd.

Contact:86-0536-6777557

Address:Zhuliu Industiral Park,Changle County
Chemsky（shanghai）International Co.,Ltd.

Contact:0

Address:0

Relevant to this article

Chiral salen-metal complexes as novel catalysts for the asymmetric synthesis of α-amino acids under phase transfer catalysis conditions

Doi:10.1016/S0040-4020(01)00072-2
(2001)
Base-promoted aerobic oxidation of: N -alkyl iminium salts derived from isoquinolines and related heterocycles

Doi:10.1039/c9gc03629f
(2020)
Doi:10.1016/S0040-4039(00)70124-9
(1966)
Synthesis of some new nucleosides derived from 2-mercapto benzimidazole with expected biological activity

Doi:10.13005/ojc/330519
(2017)
Antimalarials. 13. 5-Alkoxy Analogues of 4-Methylprimaquine

Doi:10.1021/jm00350a016
(1982)
Synthesis of enantiopure 1,2-azido and 1,2-amino alcohols via regio- and stereoselective ring-opening of enantiopure epoxides by sodium azide in hot water

Doi:10.1016/j.tetasy.2015.12.002
(2016)

Article Doi