NUCLEOPHILIC SUBSTITUTION OF α-HALO-KETONES. XXIII. ACETOLYSIS OF 1-CHLORO-3-PHENOXY-1-PHENYLTHIO-2-PROPANONES. AN INTRAMOLECULAR TRANS-ACETYLATION INVOLVING PHENOXIDE ANION AS THE LEAVING GROUP

DOI: 10.1016/S0040-4020(01)88800-1

Source and publish data:

Tetrahedron p. 3709 - 3716 (1984)

Update date:2022-08-04

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Authors:

Pusino, Alba

Saba, Antonio

Rosnati, Vittorio

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Article abstract of DOI:10.1016/S0040-4020(01)88800-1

The acetolyses of α-chloro-ketones 1a-c, 2a-c, 9a and 11a have been investigated parallely.Several aspects of the mechanisms involved in chlorine normal and cine substitution have been elucidated.Intramolecular trans-acetylation, ultimately leading to fra

Full text of DOI:10.1016/S0040-4020(01)88800-1

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