Heterodienophiles. 10. Stereoselectivity in the 1,4-Cycloaddition of N-(Ethoxycarbonyl)-C-alkylaldiminium Ions with Cyclohexa-1,3-diene

DOI: 10.1021/jo00211a021

Source and publish data:

Journal of Organic Chemistry p. 1888 - 1894 (1985)

Update date:2022-08-04

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Authors:

Krow, Grant R.

Henz, Kenneth J.

Szczepanski, Steven W.

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Article abstract of DOI:10.1021/jo00211a021

The first systematic investigation of the stereochemistry of cycloaddition reactions of C-alkylaldiminium ions 2 is described.N-(Ethoxycarbonyl)-3-exo- and N-(ethoxycarbonyl)-3-endo-alkyl-5,6-dehydroisoquinuclidines 3 and 4 are formed from alkylidenebis(u

Full text of DOI:10.1021/jo00211a021

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