Reactions of N-sulfinylfluoroalkanesulfonyl amines with nucleophiles containing reactive hydrogen

Article abstract of DOI:10.1016/0022-1139(93)03060-Y

The reactions of N-sulfinylfluoroalkanesulfonyl amines, R_fSO2NSO (1), with malonate or dialkyl phosphite gave 1:1 adducts R_fSO2NHS(O)Nu , and with alcohols or phenols formed R_fSO2NH2 and the sulfites O=S(OR)2 by double addition .Trans-sulfinylation occurred during the reaction of 1 with anilines (C6H5NH2, 4-FC6H4NH2 and C6F5NH2).