Reactions of N-sulfinylfluoroalkanesulfonyl amines with nucleophiles containing reactive hydrogen

DOI: 10.1016/0022-1139(93)03060-Y

Source and publish data:

Journal of Fluorine Chemistry p. 85 - 88 (1994)

Update date:2022-08-04

Topics:

Authors:

Li, Ai-Wen

Xu, Bin Xu, Bin

Wang, Chao-Xian

Zhu, Shi-Zheng

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-1139(93)03060-Y

The reactions of N-sulfinylfluoroalkanesulfonyl amines, R_fSO2NSO (1), with malonate or dialkyl phosphite gave 1:1 adducts R_fSO2NHS(O)Nu , and with alcohols or phenols formed R_fSO2NH2 and the sulfites O=S(OR)2 by double addition .Trans-sulfinylation occurred during the reaction of 1 with anilines (C6H5NH2, 4-FC6H4NH2 and C6F5NH2).

Full text of DOI:10.1016/0022-1139(93)03060-Y

Products guided by the article

Product name:Phenol, pentafluoro-, sulfite (2:1)

Cas No:96157-57-2

R&D Labs maybe for 96157-57-2

Wuhan Hanye Chemical New Material Co.,Ltd

Contact:+86-27-85308141

Address:LiuDian, Panlongcheng Economic Development Zone, HuangPi district, Wuhan, Hubei 430311 P.R.China
Second Pharma Co., Ltd

Contact:+86-575-82733999 0575-82732999

Address:hangzhou gulf fine chemical zone,shangyu city,zhejiang province
Jiaxing Taixin Pharmaceutical Chemical Co., Ltd

Contact:0573-82613601

Address:Chemical Park, Jiaxing, Zhejiang, China
shanghai hekang chemical co.ltd

Contact:021-54173790

Address:328 WuHe Road, Building #A, 2nd Floor, Minhang, Shanghai 201109, China
SHANGHAI ARCADIA BIOTECHNOLOGY LTD.

Contact:+86-21-61353236

Address:SUITE 901, BUILDING WENSLI, 1378 LU JIA BANG RD, SHANGAHI 200011, P.R.CHINA

Relevant to this article

1,3,4-Benzotriazepinones. Formation and rearrangement

Doi:10.1002/jhet.5570210649
(1984)
Stereochemical fate of chiral-methyl valine in the ring expansion of penicillin N to deacetoxycephalosporin C

Doi:10.1021/ja00302a026
(1985)
Photochemistry of Phenyl Azide: The Role of Singlet and Triplet Phenylnitrene as Transient Intermediates

Doi:10.1021/ja00273a037
(1986)
Synthesis of symmetric triarylmethane derivatives catalyzed by AIL ionic liquid

Doi:10.1007/s00706-017-2053-2
(2018)
Hexahydropyrimidines. L. Preparation of 2-substituted-1,3-bis(p-dimethylamino-benzyl)-hexahydropyrimidines.

Doi:10.1002/jps.2600511113
(1962)
Doi:10.1002/hlca.19630460412
(1963)

Article Doi