Reactions of N-sulfinylfluoroalkanesulfonyl amines with nucleophiles containing reactive hydrogen

DOI: 10.1016/0022-1139(93)03060-Y

Source and publish data:

Journal of Fluorine Chemistry p. 85 - 88 (1994)

Update date:2022-08-04

Topics:

Authors:

Li, Ai-Wen

Xu, Bin Xu, Bin

Wang, Chao-Xian

Zhu, Shi-Zheng

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-1139(93)03060-Y

The reactions of N-sulfinylfluoroalkanesulfonyl amines, R_fSO2NSO (1), with malonate or dialkyl phosphite gave 1:1 adducts R_fSO2NHS(O)Nu , and with alcohols or phenols formed R_fSO2NH2 and the sulfites O=S(OR)2 by double addition .Trans-sulfinylation occurred during the reaction of 1 with anilines (C6H5NH2, 4-FC6H4NH2 and C6F5NH2).

Full text of DOI:10.1016/0022-1139(93)03060-Y

Products guided by the article

Product name:Phenol, pentafluoro-, sulfite (2:1)

Cas No:96157-57-2

R&D Labs maybe for 96157-57-2

Hangzhou yi lu biont technology Co., LTD

Contact:+86-571-88152630

Address:Hangzhoushi HuafengRoad Yicheng3Building1001room.
Shenzhen HwaGen Pharmaceutical Co., Ltd

website:http://www.rafflespt.com

Contact:+86-752-5538396

Address:Guangdong Huizhou China
Shandong Wanda Organosilicon New Material Co., Ltd

Contact:+86-21-54177116;54302881

Address:R1318 Greenland No. 3 Lane 58 Xinjian East Rd., Minhang
Changzhou LanXu Chemical Co.,ltd.(expird)

Contact:86-0519-86330911,13656129734,15261186386

Address:Room 524, Depart.Chemical, Changzhou Science and Eductaion town, Jiangsu, China;Factory: Haian Fine Chemical Industry Park,Nantong,Jiangsu,China
Chengdu D-Innovation Pharmaceutical Co., Ltd

Contact:86-28-85105536

Address:1001, B6, No.88 Keyuan South Road, Chengdu Hi-Tech Zone

Relevant to this article

1,3,4-Benzotriazepinones. Formation and rearrangement

Doi:10.1002/jhet.5570210649
(1984)
Stereochemical fate of chiral-methyl valine in the ring expansion of penicillin N to deacetoxycephalosporin C

Doi:10.1021/ja00302a026
(1985)
Photochemistry of Phenyl Azide: The Role of Singlet and Triplet Phenylnitrene as Transient Intermediates

Doi:10.1021/ja00273a037
(1986)
Synthesis of symmetric triarylmethane derivatives catalyzed by AIL ionic liquid

Doi:10.1007/s00706-017-2053-2
(2018)
Hexahydropyrimidines. L. Preparation of 2-substituted-1,3-bis(p-dimethylamino-benzyl)-hexahydropyrimidines.

Doi:10.1002/jps.2600511113
(1962)
Doi:10.1002/hlca.19630460412
(1963)

Article Doi