Intramolecular C-H Insertions of Alkylidenecarbenes. 2. Stereochemistry and Isotope Effects

DOI: 10.1021/jo00214a029

Source and publish data:

Journal of Organic Chemistry p. 2557 - 2563 (1985)

Update date:2022-08-04

Topics:

Authors:

Gilbert, John C.

Giamalva, David H.

Baze, Mark E.

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Article abstract of DOI:10.1021/jo00214a029

The stereochemistry of the intramolecular 1,5 carbon-hydrogen insertion reaction of alkylidenecarbenes to form cyclopentenes has been determined.The isotope effects for two intramolecular examples of insertion reactions of this class of carbenes have been

Full text of DOI:10.1021/jo00214a029

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