Intramolecular C-H Insertions of Alkylidenecarbenes. 2. Stereochemistry and Isotope Effects

DOI: 10.1021/jo00214a029

Source and publish data:

Journal of Organic Chemistry p. 2557 - 2563 (1985)

Update date:2022-08-04

Topics:

Authors:

Gilbert, John C.

Giamalva, David H.

Baze, Mark E.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00214a029

The stereochemistry of the intramolecular 1,5 carbon-hydrogen insertion reaction of alkylidenecarbenes to form cyclopentenes has been determined.The isotope effects for two intramolecular examples of insertion reactions of this class of carbenes have been

Full text of DOI:10.1021/jo00214a029

Products guided by the article

Product name:5-bromo-5-phenyl-2-pentanone

Cas No:96455-80-0

R&D Labs maybe for 96455-80-0

suzhou BetterBioChem Co., Ltd.

website:http://www.betterbiochem.com

Contact:+86-18013506594

Address:No. 8 Building, 18 nong, Xi Yingnan Road, Pudong, Shanghai,China
Shenzhen Hongyuan Import & Export Co., Ltd.

Contact:0755-26407171

Address:Shenzhen Hongyuan Chemical New Materials Technology Co., Ltd.
Beijing Zhongshuo Pharmaceutical T & D Co.,Ltd

Contact:0086-10-64430626

Address:ea No 16, HEPINGLI,DONGCHENG DISTRICT,BEIJING,P.R.CHINA.
QUZHOU ZIO I/E CO.;LTD

Contact:13357117572

Address:No.149 Shiji dadao Road.
Shandong Wanda Organosilicon New Material Co., Ltd

Contact:+86-21-54177116;54302881

Address:R1318 Greenland No. 3 Lane 58 Xinjian East Rd., Minhang

Relevant to this article

Synthesis of phosphonate and thiophosphonate esters and amides from hydrogen-phosphinates by a novel one-pot activation-coupling-oxidation procedure

Doi:10.1021/jo00128a006
(1995)
N-Methylpiperidine N-Oxide as a Source of Nonstabilized Ylide: A New and Efficient Route to Octahydroindolizine Derivatives

Doi:10.1021/jo00216a020
(1985)
Doi:10.1021/ja00871a027
(1962)
Robust synthesis of N-sulfonylazetidine building blocks via ring contraction of α-bromo N-sulfonylpyrrolidinones

Doi:10.1021/ol5029496
(2014)
A Convenient Synthesis of 2- and 2,3-Substituted 4H-Chromen-4-ones

Doi:10.1055/s-1984-31089
(1984)
Diastereoselective Synthesis of γ-Amino Alcohols with Three Chiral Centers by Reduction of β-Amino Ketones and Derivatives

Doi:10.1021/jo00221a018
(1985)

Article Doi