Stereocontrolled Synthesis of Tetrahydrofurans and Tetrahydropyrans Using Thallium(III)-Induced Cyclizations

DOI: 10.1021/jo00214a003

Source and publish data:

Journal of Organic Chemistry p. 2416 - 2423 (1985)

Update date:2022-08-05

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Authors:

Michael, Joseph P.

Ting, Pauline C.

Bartlett, Paul A.

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Article abstract of DOI:10.1021/jo00214a003

Various substituted 4-alkenols undergo electrophilic cyclization with thallium(III) salts in a regio- and stereoselective manner. The organothallium intermediate is not isolated but undergoes dethallation with concomitant 1,2-oxygen migration, leading to

Full text of DOI:10.1021/jo00214a003

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