Stereocontrolled Synthesis of Tetrahydrofurans and Tetrahydropyrans Using Thallium(III)-Induced Cyclizations

DOI: 10.1021/jo00214a003

Source and publish data:

Journal of Organic Chemistry p. 2416 - 2423 (1985)

Update date:2022-08-05

Topics:

Authors:

Michael, Joseph P.

Ting, Pauline C.

Bartlett, Paul A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00214a003

Various substituted 4-alkenols undergo electrophilic cyclization with thallium(III) salts in a regio- and stereoselective manner. The organothallium intermediate is not isolated but undergoes dethallation with concomitant 1,2-oxygen migration, leading to

Full text of DOI:10.1021/jo00214a003

Products guided by the article

Product name:(2R*,5R*)-2-(1-acetoxy-1-methylethyl)-5-cyclohexyltetrahydrofuran

Cas No:96481-92-4

R&D Labs maybe for 96481-92-4

Springchem New Material Technology Co.,Limited

website:http://www.spring-chem.com

Contact:86-21-62885108

Address:602B, Building 1, No. 641, Tianshan Road
Binzhou Holly Pharmaceutical Co.,Ltd.

Contact:74517

Address:No.15 Dapu Road,Huangpu District Shanghai,P.R.China
NEW FORTUNE INDUSTRIAL CO.,LTD.

website:http://newfortune.lookchem.com/

Contact:+86-25-8645-9456

Address:C4-105 GREEN ISLAND FLOWER TOWN
Zibo Fuxi'er Chemical Co.,Ltd （Shanxian Fuxi'er Chemical Co.,Ltd）

Contact:+86-533-2091422

Address:Eastern 4 on the 3th Road ,Liangxiang Industrial Park, Zibo city ,Shandong,China
BrightGene Bio-Medical Technology Co., Ltd.

website:https://en.bright-gene.com/

Contact:+86-512-62551801

Address:Building C25 - C31, No. 218 Xinghu Road, Suzhou Industrial Park, Suzhou, Jiangsu, China.

Relevant to this article

Cobalt-bisoxazoline-catalyzed asymmetric kumada cross-coupling of racemic α-bromo esters with aryl grignard reagents

Doi:10.1021/ja5109084
(2014)
Oxathiirane

Doi:10.1021/ja100670q
(2010)
Decoration of β-CD-ZrO on Fe₃O₄ magnetic nanoparticles as a magnetically, recoverable and reusable catalyst for the synthesis of 2,3-dihydro-1H-perimidines

Doi:10.1007/s11164-018-3574-y
(2018)
Conjugate addition of amines to α,β-enones promoted by CeCl₃·7H₂O-NaI system supported in silica gel

Doi:10.1021/jo0108764
(2001)
3,5-Diphenyl-1,2,4-triazin-6(1H)-one: Synthesis, and X-ray and DFT-calculated structures

Doi:10.1107/S0108270112008384
(2012)
Synthesis of α-amino-cycloheptatriene-1-acetic acids and their 7-acylaminocephalosporin derivatives

Doi:10.1248/cpb.30.2579
(1982)

Article Doi