Pure and Applied Chemistry p. 1453 - 1461 (1983)
Update date:2022-07-31
Topics:
Noeth
Weber
Rasthofer
Narula
Konstantinov
A status report on tri- and dicoordinated cations of boron is presented. Tricoordinated 1,3,2-dioxaborinium salts, described in the literature, are actually tetracoordinated species. However, salts of type R//2BL multiplied by (times) X can be prepared from boron triflates R//2Btf (R equals n-C//4H//9, C//6H//5, 1,3-dimethyl-1,3,2-diazaborolidinyl) and 2,6-lutidine, or by addition of triflic acid on 2-dimethylamino-1,3,2-diazaborolidines. The formation and stabilization of dicoordinated boron cations of three types depends both on electronic and steric factors as well as on the nature of the counter ion. Ligand exchange reactions in boron chemistry under electrophilic conditions may involve dicoordinated boron species.
ChangZhou Mascotchem. Co.,Ltd.
website:http://www.mascotchem.com
Contact:86-519-85010339
Address:B-802,XingBei Building,391#,Tongjiang Middle Road New District,Changzhou,JS,China
Jinan Baozhao Pharmaceutical Co., Ltd
Contact:0086-531-86397156 82371858 82371868
Address:Huaneng Road, Jinan, Shandong ,China
NanJing Rate Biochemicals CO., LTD
Contact:+86-25-84931986
Address:NO. 1 Hongjing Road,Jiangning Science Park,Nanjing,China
Wuhan Jadechem International Trade Co.,Ltd.
website:http://www.jadechem-intl.com
Contact:+86-27-83527060
Address:Room 502,Building C11,Software new city No.8,Huacheng Avenue,East Lake High-tech development zone,Wuhan,Hubei,China
website:http://www.easchem.com
Contact:+86-731-89722861 89722891
Address:2/F-4/Bld Colorful Palace, No.605 Changsha Ave, Yuhua Area Changsha Hunan China.
Doi:10.1016/S0040-4039(00)94876-7
(1985)Doi:10.1021/acscatal.9b05567
(2020)Doi:10.1039/c39850000218
(1985)Doi:10.1055/s-1999-3121
(1999)Doi:10.1021/jm00342a033
(1963)Doi:10.1016/S0040-4020(01)96410-5
(1985)
