Pure and Applied Chemistry p. 1453 - 1461 (1983)
Update date:2022-07-31
Topics:
Noeth
Weber
Rasthofer
Narula
Konstantinov
A status report on tri- and dicoordinated cations of boron is presented. Tricoordinated 1,3,2-dioxaborinium salts, described in the literature, are actually tetracoordinated species. However, salts of type R//2BL multiplied by (times) X can be prepared from boron triflates R//2Btf (R equals n-C//4H//9, C//6H//5, 1,3-dimethyl-1,3,2-diazaborolidinyl) and 2,6-lutidine, or by addition of triflic acid on 2-dimethylamino-1,3,2-diazaborolidines. The formation and stabilization of dicoordinated boron cations of three types depends both on electronic and steric factors as well as on the nature of the counter ion. Ligand exchange reactions in boron chemistry under electrophilic conditions may involve dicoordinated boron species.
Xiamen Kaijia Imp & Exp Co., Ltd.
Contact:86-592-5101177
Address:Room406 Luhui Building No. 65 Haitian Road Huli Xiamen,China.
website:http://www.vanzpharm.com/en/index.html
Contact:86-27-84492310
Address:FANHU INDUSTRY PARK
Shanghai Harvest Chemical Ind. Co., Ltd.
Contact:021-51385350
Address:ROOM 806-807, AI LI CHEN BUILDING, No.333 JINGXIANG ROAD, PUDONG DISTRICT, 201206, SHANGHAI
Contact:86-532-68629711 13780605697
Address:NO 220 YANAN 3 ROAD,(POST ADMINISTRATION BUILDING),QINGDAO,CHINA
Shaanxi HuaTai Bio-fine chemical company Ltd
Contact:86-029-87862197
Address:No. 5, 3rd Floor, 29 Yanta North Road, Beilin Dist.
Doi:10.1016/S0040-4039(00)94876-7
(1985)Doi:10.1021/acscatal.9b05567
(2020)Doi:10.1039/c39850000218
(1985)Doi:10.1055/s-1999-3121
(1999)Doi:10.1021/jm00342a033
(1963)Doi:10.1016/S0040-4020(01)96410-5
(1985)
