A NOVEL STEREOSELECTIVE SYNTHESIS OF 1,3,5-TRIENES VIA SO2 EXTRUSION FROM SULFOLENES.

DOI: 10.1016/S0040-4039(00)94876-7

Source and publish data:

Tetrahedron Letters p. 1301 - 1304 (1985)

Update date:2022-07-31

Topics:

Authors:

Bloch, R.

Benecou, C.

Guibe-Jampel, E.

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Article abstract of DOI:10.1016/S0040-4039(00)94876-7

(E)-1,3,5-hexatriene as well as (E,E)-1,3,5-undecatriene and (E,Z)-1,3,5-undecatriene, two natural compounds isolated from the essential oils of Galbanum and Dictyoperis, were stereoselectively synthesized from sulfolenes generated by a retro-Diels-Alder reaction.

Full text of DOI:10.1016/S0040-4039(00)94876-7

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