Tetrahedron p. 1071 - 1074 (1987)
Update date:2022-08-03
Topics:
Huth, Andreas
Beetz, Ilse
Schumann, Ingrid
Thielert, Kreimhild
The carbonylation of the iodides 2a-c and 12a-b in benzyl alcohol with carbon monoxide affords the corresponding benzyl esters 3a-c and 13a-b in good yields.It is shown that 3a can be easily and selectively cleaved to the acid 4a by catalytic hydrogenation.The acid is converted to an ester, 7a, and an amide, 6a.
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