CARBONYLATION IN BENZYL ALCOHOL. A NEW AND EASY METHOD FOR THE PREPARATION OF AROMATIC BENZYL ESTERS

DOI: 10.1016/S0040-4020(01)90043-2

Source and publish data:

Tetrahedron p. 1071 - 1074 (1987)

Update date:2022-08-03

Topics:

Authors:

Huth, Andreas

Beetz, Ilse

Schumann, Ingrid

Thielert, Kreimhild

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Article abstract of DOI:10.1016/S0040-4020(01)90043-2

The carbonylation of the iodides 2a-c and 12a-b in benzyl alcohol with carbon monoxide affords the corresponding benzyl esters 3a-c and 13a-b in good yields.It is shown that 3a can be easily and selectively cleaved to the acid 4a by catalytic hydrogenation.The acid is converted to an ester, 7a, and an amide, 6a.

Full text of DOI:10.1016/S0040-4020(01)90043-2

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