Structures of Three Lithium Ester Enolates by X-ray Diffraction: Derivation of Reaction Path for Cleavage into Ketene and Alcoholate

DOI: 10.1021/ja00305a014

Source and publish data:

Journal of the American Chemical Society p. 5403 - 5409 (1985)

Update date:2022-07-29

Topics:

Authors:

Seebach, Dieter

Amstutz, Rene

Laube, Thomas

Schweizer, W. Bernd

Dunitz, Jack D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00305a014

Crystal structure analyses have been carried out for lithium enolates of the following three esters: tert-butyl propionate ((Z)-1), tert-butyl 2-methylpropionate (2), and methyl 3,3-dimethylbutanoate ((Z)-3).Enolates (Z)-1 and 2 are dimeric (with one TMED

Full text of DOI:10.1021/ja00305a014

Products guided by the article

Product name:Silane, trimethyl[[1-(1-methylethylidene)pentyl]oxy]-

Cas No:97190-48-2

R&D Labs maybe for 97190-48-2

Wuhan Pengo Technology.,Ltd.

Contact:+86-27-67841589

Address:Add: 999 Gaoxin Road, Donghu New Technology Development Zone, Wuhan City, Hubei, China
Tianjin Anda North Industrial & Business Co.Ltd.

Contact:86-22-24999306

Address:No.11 Erwei Road,Dongli Development Area,Tianjin,China
Henan Sinotech Import&Export Corporation

website:http://www.hasinotech.com

Contact:86-371-86181678

Address:No. 260, Dongming Road,Jinshui District
HOST COUNTRY LIMITED

Contact:+852 83038667

Address:Room 1502, 15th Floor, SPA Centre,53-55 Lockhart Road, Wanchai, Hong Kong
Lishui Nanming Chemical Co., Ltd(expird)

Contact:+86-0578-2134101，2697830

Address:No.19 Tongji Road Shuige Industrial zone

Relevant to this article

MODIFICATION OF SINGLET CARBENE REACTIVITIES BY SOLVENT

Doi:10.1016/S0040-4020(01)96743-2
(1985)
Access to Diverse Oxygen Heterocycles via Oxidative Rearrangement of Benzylic Tertiary Alcohols

Doi:10.1021/acs.orglett.6b00672
(2016)
Metal free, facile sulfenylation of ketene dithioacetals catalyzed by an HBr-DMSO system

Doi:10.1039/C9NJ00925F
(2019)
Enantioselective alkynylation reactions to aldehydes: The effects of aromatic substituents upon the enantioselectivity

Doi:10.1055/s-2006-950205
(2006)
Nickel-Catalyzed Cross-Electrophile Coupling of Alkyl Fluorides: Stereospecific Synthesis of Vinylcyclopropanes

Doi:10.1021/jacs.6b07567
(2016)
Synthesis of a protected trihexosyl unit: a glycosyl acceptor corresponding to the core structure of the N-linked glycan of a glycoprotein

Doi:10.1016/0008-6215(83)88397-9
(1983)

Article Doi