Structures of Three Lithium Ester Enolates by X-ray Diffraction: Derivation of Reaction Path for Cleavage into Ketene and Alcoholate

DOI: 10.1021/ja00305a014

Source and publish data:

Journal of the American Chemical Society p. 5403 - 5409 (1985)

Update date:2022-07-29

Topics:

Authors:

Seebach, Dieter

Amstutz, Rene

Laube, Thomas

Schweizer, W. Bernd

Dunitz, Jack D.

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Article abstract of DOI:10.1021/ja00305a014

Crystal structure analyses have been carried out for lithium enolates of the following three esters: tert-butyl propionate ((Z)-1), tert-butyl 2-methylpropionate (2), and methyl 3,3-dimethylbutanoate ((Z)-3).Enolates (Z)-1 and 2 are dimeric (with one TMED

Full text of DOI:10.1021/ja00305a014

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