Structures of Three Lithium Ester Enolates by X-ray Diffraction: Derivation of Reaction Path for Cleavage into Ketene and Alcoholate

DOI: 10.1021/ja00305a014

Source and publish data:

Journal of the American Chemical Society p. 5403 - 5409 (1985)

Update date:2022-07-29

Topics:

Authors:

Seebach, Dieter

Amstutz, Rene

Laube, Thomas

Schweizer, W. Bernd

Dunitz, Jack D.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00305a014

Crystal structure analyses have been carried out for lithium enolates of the following three esters: tert-butyl propionate ((Z)-1), tert-butyl 2-methylpropionate (2), and methyl 3,3-dimethylbutanoate ((Z)-3).Enolates (Z)-1 and 2 are dimeric (with one TMED

Full text of DOI:10.1021/ja00305a014

Products guided by the article

Product name:Silane, trimethyl[[1-(1-methylethylidene)pentyl]oxy]-

Cas No:97190-48-2

R&D Labs maybe for 97190-48-2

Xinchang Yueding Chemical Co., Ltd.

Contact:86-571-56926323

Address:NO.90 BEIMENCHENGWAI CHENGGUAN TOWN XINCHANG
JenKem Technology Co., Ltd.

Contact:86-10-62983737; +86-10-51287608

Address:4/F Building C, 2 Shangdi Xinxi Road
BrightGene Bio-Medical Technology Co., Ltd.

website:https://en.bright-gene.com/

Contact:+86-512-62551801

Address:Building C25 - C31, No. 218 Xinghu Road, Suzhou Industrial Park, Suzhou, Jiangsu, China.
Shanghai Rainbow Chemistry Co., Ltd.

Contact:+86-21-64968086-5815/5812

Address:3rd floor, Building 7, 251 Faladi Road, Zhangjiang Hi-Tech Park, Pudong District, Shanghai, P.R. China
Naturalin Bio-Resource Co., Ltd

website:http://www.naturalin.com

Contact:+86-0731-84430651

Address:B1-402, Lu-Valley Enterprise Square.No.27 Wenxuan Road. Lu-Valley Hi-Tech District.

Relevant to this article

MODIFICATION OF SINGLET CARBENE REACTIVITIES BY SOLVENT

Doi:10.1016/S0040-4020(01)96743-2
(1985)
Access to Diverse Oxygen Heterocycles via Oxidative Rearrangement of Benzylic Tertiary Alcohols

Doi:10.1021/acs.orglett.6b00672
(2016)
Metal free, facile sulfenylation of ketene dithioacetals catalyzed by an HBr-DMSO system

Doi:10.1039/C9NJ00925F
(2019)
Enantioselective alkynylation reactions to aldehydes: The effects of aromatic substituents upon the enantioselectivity

Doi:10.1055/s-2006-950205
(2006)
Nickel-Catalyzed Cross-Electrophile Coupling of Alkyl Fluorides: Stereospecific Synthesis of Vinylcyclopropanes

Doi:10.1021/jacs.6b07567
(2016)
Synthesis of a protected trihexosyl unit: a glycosyl acceptor corresponding to the core structure of the N-linked glycan of a glycoprotein

Doi:10.1016/0008-6215(83)88397-9
(1983)

Article Doi