Bulletin of the Chemical Society of Japan p. 1059 - 1060 (1985)
Update date:2022-08-05
Topics:
Shinkai, Seiji
Miyazaki, Kiminori
Nakashima, Mikio
Manabe, Osamu
A new photoresponsive crown ether 2 with a stilbene-cap was synthesized.The crown trans-2 could extract Li+ and Na+ into the organic phase, and UV light irradiation which produces photoisomerized cis-2 enhanced the extractability.Thus, the stilbene-cap induces the conformational change in the crown ether moiety by photoirradiation.
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