Oxyphosphorane Hydrolysis. Reversible Ring Opening of Spirophosphoranes Containing Six-Atom Rings

DOI: 10.1021/ja00304a028

Source and publish data:

Journal of the American Chemical Society p. 5198 - 5203 (1985)

Update date:2022-08-02

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Authors:

McGall, Glenn H.

McClelland, Robert A.

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Article abstract of DOI:10.1021/ja00304a028

A kinetic and mechanistic study is reported for the hydrolysis of two spirooxyphosphoranes containing six-atom rings (6-phenyl-1,5,7,11-tetraoxa-6-phosphospiro<5.5>undecane (2a) and the 3,3,9,9-tetramethyl-substituted compound (2b)).An intermediate is obs

Full text of DOI:10.1021/ja00304a028

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