Preparation of Acetals of α-Epoxyketones and Their Chemoselective Hydrolysis Into α-Epoxyketones by Acidic Moist Silica Gel

DOI: 10.1055/s-1987-27964

Source and publish data:

Synthesis p. 404 - 406 (1987)

Update date:2022-08-03

Topics:

Authors:

Lescure, Pascal

Huet, Francois

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1987-27964

Sulfur ylides react with monoacetals of α-dicarbonyl compounds to give the expected epoxyacetals in satisfactory to figh yields.These lead to α-epoxyketones by chemoselective hydrolysis by acidic moist silica gel.

Full text of DOI:10.1055/s-1987-27964

Products guided by the article

Product name:2-Dimethoxymethyl-2-phenyl-oxirane

Cas No:97228-33-6

R&D Labs maybe for 97228-33-6

HANGZHOU TOYOND BIOTECH CO., LTD

Contact:+86-571-86965177

Address:No. 189, Fengqi East Road, Hangzhou, China
MINS GROUP CO.,LIMITED

Contact:18669908765

Address:Zibo City, Shandong Province, P.R.China
SHAANXI FUJIE PHARMACEUTICAL CO.,LTD

website:http://www.fujiepharm.com

Contact:+86-29-63650906

Address:Yuanqu Yi Road, Qinghe Food Industrial Park, Sanyuan County, Shaanxi Province, China
Shanghai Bojing Chemical Co., Ltd.

Contact:021-37122233

Address:6F Buildiing 11,No.388,Baifu Road,District Fengxian.Shanghai, China.
Synchemie Co., Ltd.

website:http://www.synchemie.com/

Contact:+86-574-87642758

Address:Room 901, Yinyi Bund Building， 132 Renmin Road

Relevant to this article

REACTION OF α-HALOESTER HAVING INTERNAL DOUBLE BOND WITH THE LOW-VALENT METAL COMPLEX

Doi:10.1016/S0040-4039(00)98541-1
(1985)
Syntheses of N⁴,2',3',5'-tetraacylcytidines from N⁴-acylcytosines, via condensation with tetraacylribose and transribosylation with acylated purine nucleosides

Doi:10.1248/cpb.36.3253
(1988)
3,7-BIS-(4-TRIFLUOROMETHYLPHENYL)-1,5,3,7-DIOXADIAZOCINE: A NOVEL CYCLIC PRODUCT FROM A REACTION OF 4-TRIFLUOROMETHYLBENZENEDIAZONIUM CHLORIDE AND METHYLAMIN-FORMALDEHYDE

Doi:10.1016/S0040-4039(00)98507-1
(1985)
A New Route to Chiral Bis-tertiary Phosphine Ligands: Synthesis, Resolution, and Crystal Structure of trans-Bis-1,2-(diphenylphosphino)cyclopentane and the Nickel Adduct NiBr2

Doi:10.1039/c39830000895
(1983)
Novel palladium(0)-catalyzed polyaddition of bifunctional vinyloxiranes with 1,3-diketones. Synthesis of new polymers bearing an allyl alcohol moiety via π-allylpalladium intermediates

Doi:10.1021/ma011900i
(2002)
A mild and expeditious synthesis of amides from aldehydes using bio glycerol-based carbon as a recyclable catalyst

Doi:10.1016/j.tetlet.2012.03.051
(2012)

Article Doi