NOVEL RING TRANSFORMATION OF THIAZOLIDINE TO OXAZOLIDINE: ACYL HALIDE-PROMOTED INTRAMOLECULAR REARRANGEMENT OF 4(R)-HYDROXYMETHYL-3-METHYL-1,3-THIAZOLIDINE

DOI: 10.1016/S0040-4039(00)61951-2

Source and publish data:

Tetrahedron Letters p. 869 - 872 (1985)

Update date:2022-08-03

Topics:

Authors:

Ando, Wataru

Takata, Toshikazu

Huang, Liren

Tamura, Yoshiharu

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Article abstract of DOI:10.1016/S0040-4039(00)61951-2

An interesting transformation occurs during acylation of 4(R)-hydroxymethyl-3-methyl-1,3-thiazolidine when 4(R)-acylthiomethyl-3-methyl 1,3-oxazolidines are yielded: the reaction competing with O-acylation is controlled by the bulkiness of the acyl group.

Full text of DOI:10.1016/S0040-4039(00)61951-2

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