Journal of the Chemical Society, Dalton Transactions p. 2535 - 2538 (1988)
Update date:2022-08-03
Topics:
Bishop, Peter T.
Dilworth, Jonathan R.
Hughes, David L.
[MoCl3(NCCH3)3] reacts with an excess of 2,4,6-tri-isopropylthiophenolate in acetonitrile to give [Mo(SC 6H2Pri3-2,4,6)4(NCCH 3)] where molybdenum has been oxidized. An X-ray crystal structure determination revealed a trigonal-bipyramidal geometry about molybdenum with a CH3CN group occupying an apical site.
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