Tetrahedron Letters p. 811 - 814 (1985)
Update date:2022-08-05
Topics:
Creary, Xavier
McDonald, Steven R.
Eggers, Mark D.
α-amido mesylates generally solvolyze giving α-keto cations, bypassing cyclic ions derived from carbonyl (kΔ) participation.A possible exception is the N,N-dimethylamido mesylate derived from (S)-mandelic acid in trifluoroacetic acid which gives a small amount (9percent) of retained product.
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Doi:10.1021/acs.orglett.7b00085
(2017)Doi:10.1002/ejoc.201701155
(2017)Doi:10.1016/0008-6215(85)85134-X
(1985)Doi:10.1021/ja01526a065
(1959)Doi:10.1139/v58-227
(1958)Doi:10.1021/ja01267a025
(1939)
