Regiocontrolled Allylsilane Synthesis from Secondary Allylic Alcohol Derivatives

DOI: 10.1039/c39850000411

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 411 - 413 (1985)

Update date:2022-07-30

Topics:

Authors:

Fleming, Ian

Thomas, Andrew P.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39850000411

Unsymmetrical secondary allylic acetates and urethanes react with the dimethyl(phenyl)silylcuprate reagent to give allylsilanes with fair to good regioselectivity.

Full text of DOI:10.1039/c39850000411

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:(+/-)-(E)-2-(dimethylphenylsilyl)-3-pentene

Cas No:97946-04-8

R&D Labs maybe for 97946-04-8

Shaanxi HuaTai Bio-fine chemical company Ltd

Contact:86-029-87862197

Address:No. 5, 3rd Floor, 29 Yanta North Road, Beilin Dist.
Sichuan Highlight Fine Chemicals Co., Ltd.

Contact:+86-28-8525 1605

Address:A5-102 Airport base,388 West Airport Huang He Zhong Lu,2 Section
Hangzhou Ocean Chemical Co., Ltd.

website:http://www.hzoceanchem.com

Contact:+86-571-88025872, 28272092, 28272096

Address:Room 623 ,Building No 1 , COFCO Radius Commercial Center Xiwen Road, Xiacheng District, Hangzhou, Zhejiang Province, China
Improve Medical Technology(Nanxiong) Co., Ltd

Contact:86-751-3836997

Address:No.33, Pingan First Road, Fine Chemical Industry Base, Nanxiong City, Shaoguan, Guangdong, China
LIAONING DMSO CHEMICALS CO.,LTD.

website:http://www.chinadmso.com

Contact:+86-427-6503033

Address:FLOOR 16, BLOCK A, FINANCIAL SQUARE, XINGLONGTAI DISTRICT, PANJIN CITY, LIAONING P.R. CHINA

Relevant to this article

Photochemical Conversion of Sulfonium Salts via a 1,3-Sigmatropic Rearrangement. Photogeneration of Broensted Acids

Doi:10.1021/jo00222a031
(1985)
Synthesis of 2,4,6-Triaryl-1,3,5-dithiazines and N-Arylmethylene-1-thioacylamino-1-arylmethylamines from N,N'-Diarylmethylenearylmethanediamines and Thioamides

Doi:10.1055/s-1985-31122
(1985)
HYDROXYL-DIRECTED IODOETHERIFICATIONS OF ALLYLIC ALCOHOLS. SYNTHESIS OF ALLYLIC ALCOHOLS. SYNTHESSIS OF (+/-)-CITREOVIRAL.

Doi:10.1016/S0040-4039(00)98828-2
(1985)
Thiamorphinans II

Doi:10.1007/BF00798462
(1985)
Doi:10.1016/S0040-4020(01)93200-4
(1959)
Doi:10.1016/0040-4020(59)85007-9
(1959)

Article Doi