Journal of Organic Chemistry p. 2762 - 2765 (1994)
Update date:2022-08-05
Topics:
DesMarteau, Darryl D.
Petrov, Viacheslav A.
Montanari, Vittorio
Pregnolato, Massimo
Resnati, Giuseppe
Sulfides are oxidized to sulfoxides by stoichiometric amounts of perfluoro-cis-2,3-dialkyloxaziridines 2.The reactions proceed at -40 deg C with nearly complete selectivity and very good yields.Sulfoxides are also oxidized easily by 2 under mild conditions to corresponding sulfones.The oxidation of some bioactive sulfides (promazine, albendazole, biotin, and others) is also reported.
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