Mild and Selective Oxygenation of Sulfides to Sulfoxides and Sulfones by Perfluoro-cis-2,3-dialkyloxaziridines

DOI: 10.1021/jo00089a020

Source and publish data:

Journal of Organic Chemistry p. 2762 - 2765 (1994)

Update date:2022-08-05

Topics:

Authors:

DesMarteau, Darryl D.

Petrov, Viacheslav A.

Montanari, Vittorio

Pregnolato, Massimo

Resnati, Giuseppe

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00089a020

Sulfides are oxidized to sulfoxides by stoichiometric amounts of perfluoro-cis-2,3-dialkyloxaziridines 2.The reactions proceed at -40 deg C with nearly complete selectivity and very good yields.Sulfoxides are also oxidized easily by 2 under mild conditions to corresponding sulfones.The oxidation of some bioactive sulfides (promazine, albendazole, biotin, and others) is also reported.

Full text of DOI:10.1021/jo00089a020

Products guided by the article

Product name:((azidomethyl)sulfonyl)benzene

Cas No:98279-78-8

R&D Labs maybe for 98279-78-8

RongCheng Tianyu Technology Co.,Ltd.

Contact:86-631-7519595

Address:220Ping Donghai Road RongChengCity,ShangDong Province China
FREEBARQUE DEVELOPMENT GROUP LIMITED

Contact:+86(0)10-5109 5335 or 5109 5345

Address:Room602,Block1-B,LINGDI OFFICE,NO.13 BEIYUAN ROAD
NEW FORTUNE INDUSTRIAL CO.,LTD.

website:http://newfortune.lookchem.com/

Contact:+86-25-8645-9456

Address:C4-105 GREEN ISLAND FLOWER TOWN
Zhejiang Kente Chemical Co.,Ltd.

Contact:86-0576-87651912

Address:No.7, Fengxi West Road, Modern Industrial Zone
shandong zhongke taidou chemical co.,ltd

Contact:86-531-88682301

Address:Jinan shandong Province CHina

Relevant to this article

Doi:10.1021/ja01463a038
(1961)
Fluorodiazadiphosphetidines, 14: Nucleophilic Substitution Reactions of 1-Chloromethyl-2,2,2,4,4,4-hexafluoro-3-methyl-1,3,2λ⁵,4λ⁵-diazadiphosphetidine and 1,3-Bis-(chloromethyl)-2,2,2,4,4,4-hexafluoro-1,3,2λ⁵,4λ⁵

Doi:10.1007/BF00798451
(1985)

One-step conversion of silyl/THP ethers into the corresponding acetates

Doi:10.1016/S0040-4039(01)00967-4
(2001)
Unsaturated Crown Ethers. 3. Syntheses of Stilbeno Crown Ethers

Doi:10.1021/jo00225a035
(1985)
Doi:10.1021/jo01032a040
(1964)
A Convenient Method for the Preparation of Conjugated Olefins from Allylic Acetates and Aldehydes. Synthesis of Pellitorine

Doi:10.1246/bcsj.57.3013
(1984)

Article Doi