CARBOCYCLIZATION REACTIONS OF 1-NITROCYCLOALKENES AND CROSS-CONJUGATED DIENAMINES

DOI: 10.1016/S0040-4020(01)96544-5

Source and publish data:

Tetrahedron p. 1415 - 1422 (1985)

Update date:2022-08-04

Topics:

Authors:

Mezzetti, A.

Nitti, P.

Pitacco, G.

Valentin, E.

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Article abstract of DOI:10.1016/S0040-4020(01)96544-5

Dodecahydro-8a-nitro-as-indacen-4(2H)-one, dodecahydro-9a-nitro-4H-benzinden-4-one, dodecahydro-9b-nitro-5H-benzinden-5-one and dodecahydro-4a-nitro-9(1H)-phenanthrenone of cis-anti-cis backbone are synthesized in quantitative yield by cycloaddition reaction of 1-nitro-cyclopent-1-ene and 1-nitro-cyclohex-1-ene with 1-(cyclopenten-1-yl)- and 1-(cyclohexen-1-yl)-1-(piperidin-1-yl)-ethenes respectively.The enamine intermediates are also isolated and characterized.

Full text of DOI:10.1016/S0040-4020(01)96544-5

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Product name:Piperidine, 1-[1-(1-cyclohexen-1-yl)-2-(2-nitrocyclohexyl)ethenyl]-

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