Journal of the Chemical Society. Chemical communications p. 1308 - 1309 (1983)
Update date:2022-09-26
Topics:
Holah, David G.
Hughes, Alan N.
Maciaszek, Stanislaw
Magnuson, Vincent R.
The title compound, obtained as one of several intermediates in a complex sequence of reactions involving CoII, NaBH4, and α,ω-bis(diphenylphosphino)alkanes, is isolated as a phosphine-bridged binuclear species in which each of two tetrahydroborato groups also bridges the two CoI units via the previously unknown M-H-BH2-H-M type of linkage; an additional and unexpected feature of the X-ray crystal structure is that one hydrogen atom of each of the two central BH2 groups also acts as a bridging ligand.
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Doi:10.1002/ardp.19853180903
(1985)Doi:10.1016/S0040-4039(00)98961-5
(1985)Doi:10.1071/CH05107
(2005)Doi:10.1021/ja00261a023
(1986)Doi:10.1039/d0nj05699e
(2021)Doi:10.1016/S0008-6215(00)80546-7
(1982)
