CHIRAL PROPIONATE ENOLATE EQUIVALENTS FOR THE STEREOSELECTIVE SYNTHESIS OF THREO- OR ERYTHRO-α-METHYL-β-HYDROXY ACIDS.

DOI: 10.1016/S0040-4039(00)94797-X

Source and publish data:

Tetrahedron Letters p. 2125 - 2128 (1985)

Update date:2022-09-26

Topics:

Authors:

Davies, Stephen G.

Dordor-Hedgecock, Isabelle M.

Warner, Peter

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Article abstract of DOI:10.1016/S0040-4039(00)94797-X

The aluminium and copper enolates derived from (n⁵-C5H5)Fe(CO)(PPh3)COCH2CH3 are chiral propionate enolate equivalents which on reaction with aldehydes (RCHO, R=Me, Et, ⁱPr, ^tBu) provide stereoselective sytheses of threo-

Full text of DOI:10.1016/S0040-4039(00)94797-X

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