An Approach to the Synthesis of Bactobolin and the Total Synthesis of N-Acetylactinobolamine: Some Remarkably Stable Hemiacetals

DOI: 10.1021/jo00380a025

Source and publish data:

Journal of Organic Chemistry p. 622 - 635 (1987)

Update date:2022-08-03

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Authors:

Askin, David

Angst, Christof

Danishefsky, Samuel

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Article abstract of DOI:10.1021/jo00380a025

The key steps in the synthesis of N-acetylactinobolamine were the siloxy-Cope rearrangemnt 17 --> 18 and the transformation of pseudoglycal 54, via its glycosyl azide derivative 55, to hemiacetal 56.This hemiacetal, as well as closely related hemicaetals

Full text of DOI:10.1021/jo00380a025

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