Journal of Organic Chemistry p. 622 - 635 (1987)
Update date:2022-08-03
Topics:
Askin, David
Angst, Christof
Danishefsky, Samuel
The key steps in the synthesis of N-acetylactinobolamine were the siloxy-Cope rearrangemnt 17 --> 18 and the transformation of pseudoglycal 54, via its glycosyl azide derivative 55, to hemiacetal 56.This hemiacetal, as well as closely related hemicaetals
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Doi:10.1002/hlca.19880710528
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