Stereocontrolled Synthesis of a Polyether Fragment

DOI: 10.1021/jo00225a040

Source and publish data:

Journal of Organic Chemistry p. 5179 - 5183 (1985)

Update date:2022-08-05

Topics:

Authors:

Bartlett, Paul A.

Holm, Kjetil H.

Morimoto, Akira

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00225a040

A sequence utilizing selenolactonization of olefinic acid 4, Ireland-Claisen rearrangement of ketal ester 9, iodolactonization / epoxidation of olefinic acid 10, and regioselective hydrolysis of epoxide 15b is described for the stereocontrolled conversion of meso-2,4-dimethylglutaric anhydride to racemic tetrahydropyran lactone 1.

Full text of DOI:10.1021/jo00225a040

Products guided by the article

Product name:(3R^*,5S^*)-5-<(2R^*,3R^*,5S^*,6R^*)-6-methoxy-3,5-dimethyl-6-(benzyloxymethyl)-2,3,4,5-tetrahydropyran-2-yl>-3-methyl-4,5-dihydro-2(3H)-furanone

Cas No:99032-06-1

R&D Labs maybe for 99032-06-1

Chengdu D-Innovation Pharmaceutical Co., Ltd

Contact:86-28-85105536

Address:1001, B6, No.88 Keyuan South Road, Chengdu Hi-Tech Zone
TIANJIN DONGRUXIANG MINERALS MARKETING CO.,LTD(expird)

Contact:22-58516360

Address:tianjin
Changsha Nutritopper Bio Technology Co.,Ltd.

Contact:+86-731-87803543

Address:East 1st Street, Baima Road, Ningxiang County
Jiacheng-Chem Enterprises Limited(expird)

Contact:86-571-86711508

Address:19 Floor, CIBC Holley International Building, No. 198,Wuxing Road, Hangzhou, China,310020
Evergreen Chemical Industry Ltd.

Contact:86-553-4918210

Address:6#2-602 Wanhaobailing

Relevant to this article

Synthesis and anti-ulcer activities of sodium alkylazulene sulfonates

Doi:10.1248/cpb.36.641
(1988)
Reactions of p-Toluenesulfonates with Lithium Triethylborohydride. Visible and Hidden Rearrangements

Doi:10.1021/jo00350a044
(1985)
α-Lithiation of N-Arylmethylimidazoles and Triazoles: A General Method for the Synthesis of 1,2-Diaryl-1-(N-azolyl)-ethanes

Doi:10.1055/s-1985-31187
(1985)
Rational design, synthesis and biological evaluation of modular fluorogenic substrates with high affinity and selectivity for PTP1B

Doi:10.1002/cbic.201400033
(2014)
Photoinduced Methanol-Incorporated Cyclization of N-(3-Phenylallyl)arenedicarboximides

Doi:10.1021/jo00350a008
(1985)
Palladium-Catalyzed Ortho-Alkoxylation of N-Benzoyl α-Amino Acid Derivatives at Room Temperature

Doi:10.1021/acs.joc.6b02257
(2017)

Article Doi