Stereocontrolled Synthesis of a Polyether Fragment

DOI: 10.1021/jo00225a040

Source and publish data:

Journal of Organic Chemistry p. 5179 - 5183 (1985)

Update date:2022-08-05

Topics:

Authors:

Bartlett, Paul A.

Holm, Kjetil H.

Morimoto, Akira

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Article abstract of DOI:10.1021/jo00225a040

A sequence utilizing selenolactonization of olefinic acid 4, Ireland-Claisen rearrangement of ketal ester 9, iodolactonization / epoxidation of olefinic acid 10, and regioselective hydrolysis of epoxide 15b is described for the stereocontrolled conversion of meso-2,4-dimethylglutaric anhydride to racemic tetrahydropyran lactone 1.

Full text of DOI:10.1021/jo00225a040

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