Journal of Organic Chemistry p. 126 - 134 (2017)
Update date:2022-08-05
Topics:
Li, Shuangjie
Zhu, Wei
Gao, Feng
Li, Chunpu
Wang, Jiang
Liu, Hong
An efficient palladium-catalyzed ortho-alkoxylation of N-benzoyl α-amino acid derivatives at room temperature has been explored. This novel transformation, using amino acids as directing groups, Pd(OAc)2 as catalyst, alcohols as the alkoxylation reagents, and PhI(OAc)2 as the oxidant, showed wide generality, good functional tolerance, and high monoselectivity and regioselectivity.
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