Journal of Physical Chemistry p. 75 - 78 (1986)
Update date:2022-08-04
Topics:
Liu, Michael T. H.
Subramanian, R.
Thermolysis and photolysis of 3-bromo-3-benzyldiazirine with tetramethylethylene in isooctane yielded E- and Z-β-bromostyrene and 1-benzyl-1-bromo-2,2,3,3-tetramethylcyclopropane.The intramolecular-intermolecular rate constants derived from the thermolysis and photolysis, when applied to an Arrhenius plot, fall on the same straight line.An A factor of 1012.1 s-1 and an activation energy of 4.7 kcal mol-1 were obtained for the 1,2-H migration in benzylbromocarbene.
View Morepuyang hongda shengdao new material co.,ltd.
Contact:+86-393- 4896278
Address:No.29 East Zhongyuan Road
Shanghai Dianyang Industry Co.,ltd
Contact:+86 21 6492 4669
Address:Chejing RD, Songjiang District, Shanghai, China
SuZhou Ascepion Pharmaceuticals, Inc.(expird)
Contact:0512-86881668
Address:Building C,68Xingqing Road,Suzhou,China.
Shanghai Micro-mega Industry Co., Ltd.
Contact:0086-21-34628682;57153848
Address:Rm413,No.413,West Meilong Road, Minhang District,Shanghai P R China
shijiazhuang shuanglian chemical industry co.,ltd
Contact:0311-82190302
Address:Luquan Intersection , Shijiazhuang--Taiyuan Expressway，Shijiazhuang City
Doi:10.1007/BF01171055
(1985)Doi:10.1021/jo01095a627
(1958)Doi:10.1246/bcsj.30.537
(1957)Doi:10.1021/jo01100a005
(1958)Doi:10.1039/b713244c
(2007)Doi:10.1016/S0040-4039(01)02244-4
(2002)
