Journal of Physical Chemistry p. 75 - 78 (1986)
Update date:2022-08-04
Topics:
Liu, Michael T. H.
Subramanian, R.
Thermolysis and photolysis of 3-bromo-3-benzyldiazirine with tetramethylethylene in isooctane yielded E- and Z-β-bromostyrene and 1-benzyl-1-bromo-2,2,3,3-tetramethylcyclopropane.The intramolecular-intermolecular rate constants derived from the thermolysis and photolysis, when applied to an Arrhenius plot, fall on the same straight line.An A factor of 1012.1 s-1 and an activation energy of 4.7 kcal mol-1 were obtained for the 1,2-H migration in benzylbromocarbene.
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