Tetrahedron Letters p. 3715 - 3718 (1985)
Update date:2022-09-26
Topics:
Suginome, Hiroshi
Yamada, Shinji
We describe a new general method for the synthesis of medium-sized lactones under mild conditions involving β-scission of alkoxy radicals derived from catacondensed lactols as a key step and its application to an efficient new synthesis of a naturally occurring 10-membered lactone, phoracantholide I <(+/-)-decan-9-olide>.
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Doi:10.1021/ja01543a027
(1958)Doi:10.1021/jo01091a002
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(2021)Doi:10.1007/BF01897469
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