
Journal of the Chemical Society. Chemical communications p. 799 - 800 (1985)
Update date:2022-07-31
Topics:
Banks, Malcolm R.
Hudson, Robert F.
The reaction of N,N-dialkylhydroxylamines with sulphinyl chlorides proceeds via an O-sulphinylated hydroxylamine intermediate, which has been isolated and characterised by n.m.r. spectroscopy; rearrangement of this intermediate to the sulphonamide has been shown to involve an aminyl radical.
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Doi:10.1055/s-0036-1589066
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(1985)