α,b-Epoxy Sulfoxides as Useful Intermediates in Organic Synthesis. III. A Novel Synthesis of α-Amino Ketones and α-Amino Aldehydes by Aminolysis of α,b-Epoxy Sulfoxides

Article abstract of DOI:10.1246/bcsj.59.457

Aminolysis of α,b-epoxy sulfoxides, easily prepared from 1-chloroalkyl phenyl sulfoxides or chloromethyl phenyl sulfoxide and carbonyl compounds, with alkyl-or arylamines afforded α-amino ketones or α-amino aldehydes in good yields.Treatment of thus obtai