Reversed Stereochemical Course of the Michael Addition of Cyclohexanone to β-nitrostyrenes by Using 1-(Trimethylsiloxy)cyclohexene/Dichloro(diisopropoxy)titanium

DOI: 10.1002/hlca.19850680205

Source and publish data:

Helvetica Chimica Acta p. 319 - 324 (1985)

Update date:2022-08-02

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Authors:

Seebach, Dieter

Brook, Michael A.

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Article abstract of DOI:10.1002/hlca.19850680205

Induced by a stoichiometric excess of dichloro(diisopropoxy)titanium, 1-(trimethylsiloxy)cyclohexene and p-substituted β-nitrostyrenes (Y=H, CH3, CH3O, CN) combine in CH2Cl2 solution at -90 deg preferentially with relative topicity ul - opposite to the co

Full text of DOI:10.1002/hlca.19850680205

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