Base-Mediated Generation of Ketenimines from Ynamides: Direct Access to Azetidinimines by an Imino-Staudinger Synthesis

DOI: 10.1002/chem.201702545

Source and publish data:

Chemistry - A European Journal p. 12991 - 12994 (2017)

Update date:2022-08-04

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Authors:

Romero, Eugénie

Minard, Corinne

Benchekroun, Mohamed

Ventre, Sandrine

Retailleau, Pascal

Dodd, Robert H.

Cariou, Kevin

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Article abstract of DOI:10.1002/chem.201702545

Ynamides were used as precursors for the in situ generation of highly reactive ketenimines that could be trapped with imines in a [2+2] cycloaddition. This imino-Staudinger synthesis led to a variety of imino-analogs of β-lactams, namely azetidinimines (2

Full text of DOI:10.1002/chem.201702545

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