Tetrahedron Letters p. 6639 - 6642 (1995)
Update date:2022-08-05
Topics:
Taber
Taber, Douglass F.
Wang
We predicted (ZINDO) that the major diastereomer from the equilibrating cyclozirconation of the α-terpineol derived diene 1 should be, after oxygenation, the diol 2. We have confirmed this by converting 2 to (+)-elemol 8. The diastereomeric control of the cyclozirconation under kinetic conditions is also striking, providing diol 3.
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