Reactivity of the Actinoid-Carbon ? Bond: Reaction of 2MCH2Si(Me)2NSiMe3 with Acidic Hydrogen, Ready C-H Activation

DOI: 10.1039/c39850000914

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Journal of the Chemical Society. Chemical communications p. 914 - 916 (1985)

Update date:2022-08-05

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Authors:

Dormond, Alain

Bouadili, Abdel Aziz El

Moise, Claude

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Article abstract of DOI:10.1039/c39850000914

The metal-carbon bond of the four-membered metallacycles <(Me3Si)2N>2M^<*>CH2Si(Me)2N^<*>SiMe3 (M = U, Th) reacts under mild conditions with acidic hydrogens of alcohols, phenols, and alkynes, with pyridine to give the orthometallated

Full text of DOI:10.1039/c39850000914

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Product name:[(C₅H₅)2U(NC₆H₁₁)C(CH₂)Si(CH₃)2NSi(CH₃)3]

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SYNTHESIS OF 10-PHTHALIMIDOALKYLTETRAHYDROPYRIMIDO<1,2-a>INDOLES

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