Stereocontrolled Total Syntheses of (-)-Hobartine and (+)-Aristoteline via an Intramolecular Nitrone-Olefin Cycloaddition

DOI: 10.1021/jo00350a103

Source and publish data:

Journal of Organic Chemistry p. 5900 - 5902 (1985)

Update date:2022-08-02

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Authors:

Gribble, Gordon W.

Barden, Timothy C.

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Article abstract of DOI:10.1021/jo00350a103

The Aristotelia alkaloids (-)-hobartine and (+)-aristoteline have been synthesized from indole and (S)-1-p-menthen-8-ylamine (7) in 11 steps (19percent) via an intramolecular nitrone-olefin 1,3-dipolar cycloaddition.

Full text of DOI:10.1021/jo00350a103

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