One-step Synthesis of Tricyclo3,8>undecan-4,11-diones by Three Consecutive Michael Reactions. A Formal Synthesis of (+/-)-Seychellene

DOI: 10.1039/c39850001047

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1047 (1985)

Update date:2022-08-04

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Authors:

Hagiwara, Hisahiro

Okano, Akihiro

Uda, Hisashi

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Article abstract of DOI:10.1039/c39850001047

Divinylketone and the trimethylsilyl enol ethers of cyclohex-2-en-1-ones undergo Lewis acid assisted triple Michael reactions yielding tricyclo<5.3.1.0^3,8>undecan-4,11-diones; the application of this reaction enabled a formal synthesis of (+/-)

Full text of DOI:10.1039/c39850001047

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