One-step Synthesis of Tricyclo3,8>undecan-4,11-diones by Three Consecutive Michael Reactions. A Formal Synthesis of (+/-)-Seychellene

DOI: 10.1039/c39850001047

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1047 (1985)

Update date:2022-08-04

Topics:

Authors:

Hagiwara, Hisahiro

Okano, Akihiro

Uda, Hisashi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39850001047

Divinylketone and the trimethylsilyl enol ethers of cyclohex-2-en-1-ones undergo Lewis acid assisted triple Michael reactions yielding tricyclo<5.3.1.0^3,8>undecan-4,11-diones; the application of this reaction enabled a formal synthesis of (+/-)

Full text of DOI:10.1039/c39850001047

View Article Online / Journal Homepage / Table of Contents for this issue

Products guided by the article

Product name:2-Cyclohexen-1-one, 3,5,5-trimethyl-6-(3-oxo-4-pentenyl)-

Cas No:99794-41-9

R&D Labs maybe for 99794-41-9

Nanjing Fayekong Chemcial Co.,Ltd(expird)

Contact:86-25-58813444

Address:Rm 1503, Unit 1, Building 5, Zijinnanyuan, Nanjing, Jiangsu, China
Shanghai Sunwise Chemical Co., Ltd

website:http://www.sunwisechem.com

Contact:86-021-33883180

Address:Room 10E, Building G, Westlink Center, No. 2337 Gudai Road, Minhang District, Shanghai, China PC: 201100
Hubei Lingsheng Pharmaceuticals Co., Ltd.

Contact:+86-0710-3538058

Address:Xiangyang City Xiangcheng Economic Development Zone, Hubei Province
Nanjing Capatue Chemical Co., Ltd

Contact:+86-25-86371192 +86-025-85720158

Address:No.20 Jiangjun Avenue, Jiangning Economic & Technical Development Zone
Yancheng Smiling Imp & Exp Co., Ltd.

Contact:+86-515-83173586

Address:Rm1207, BLD#03, Phoenix Plaza, Juheng Road, Yancheng, Jiangsu, P.R. China

Relevant to this article

Dimers of highly π-loaded organoimido d¹ metal radicals of niobium, tantalum, molybdenum, tungsten, and rhenium: The context of the cyclopentadienyl imido ligand analogy

Doi:10.1016/S0022-328X(02)01423-7
(2002)
New stereoselective beta-glycosylation via a vinyl oxirane derived from D-glucal.

Doi:10.1021/ol026648t
(2002)
Enantioselective Diels-Alder reactions of enals: Fighting species multiplicity of the catalyst with donor solvents

Doi:10.1016/S0957-4166(00)86117-0
(1991)
Synthesis of functionalized indole- and benzo-fused heterocyclic derivatives through anionic benzyne cyclization

Doi:10.1002/1521-3765(20020503)8:9<2034::AID-CHEM2034>3.0.CO;2-I
(2002)
Reactivity of [Ru₂(CO)₆(μ-PFu₂)(μ- η¹,η²-Fu)] (Fu = 2-furyl) towards diphosphanes - Substitution, polymerisation, cyclometallation and elimination reactions

Doi:10.1002/1099-0682(200208)2002:8<2103::AID-EJIC2103>3.0.CO;2-G
(2002)
Stepwise interfacial self-assembly of nanoparticles via specific DNA pairing

Doi:10.1039/b705094a
(2007)

Article Doi