Stepwise Metal-promoted Conversion of η2-CS2 into η2-SO. Synthesis and Crystal Structure of the Complex 2*HCONMe2

DOI: 10.1039/c39850001024

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Journal of the Chemical Society. Chemical communications p. 1024 - 1025 (1985)

Update date:2022-08-03

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Authors:

Bianchini, Claudio

Mealli, Carlo

Meli, Andrea

Sabat, Michal

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Article abstract of DOI:10.1039/c39850001024

Nucleophilic attack by PEt3 at the carbon atom of the η²-CS2 ligand in (triphos)RhCl(η²-CS2) yields the η¹-phosphoniodithiocarboxylate complex (triphos)RhCl(S2CPEt3), which reacts with dioxygen to

Full text of DOI:10.1039/c39850001024

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