Carbohydrate Research p. 221 - 234 (1982)
Update date:2022-08-11
Topics:
Aerts, Guido M.
Opstal, Omer Van
Bruyne, Clement K. De
The effect of phenols on the hydrolysis of substituted phenyl β-D-gluco- and β-D-xylo-pyranosides by β-D-glucosidase from Stachybotrys atra has been investigated.Depending on the glycon part of the substrate and on the phenol substituent, the hydrolysis is either inhibited or activated.With aryl β-D-glucopyranosides, such transfer does not occur when phenols are used as acceptors, but it does occur with anilines.A two-steps mechanism, in which the first step is partially reversible, is proposed to explain these observations.A qualitative analysis of the various factors determing the overall effect of the phenol is given.
View More
Doi:10.1016/j.poly.2010.07.019
(2010)Doi:10.1021/ja01156a051
(1951)Doi:10.1021/ja993023q
(1999)Doi:10.1021/jacs.6b12569
(2017)Doi:10.1021/jacs.6b07927
(2016)Doi:10.1246/bcsj.77.801
(2004)
