An easy and efficient method for cleavage of carbon-nitrogen double bonds under non-aqueous and neutral conditions

Article abstract of DOI:10.1080/00397919808004413

1-Benzyl-4-aza-1-azoniabicyclo[2.2.2]octane periodate (BAABCP) (1), readily prepared as an orange solid from commercially available DABCO (1,4- diazabicyclo [2.2.2]octane, performs oxidation in anhydrous conditions. Under these conditions, the reagent converts phenylhydrazones, p-phenylhydrazones, semicarbazones, and β-keto sulfoxide hydrazones to the corresponding carbonyl compounds and β-keto sulfoxides respectively, the yields and enantioselectivity are excellent.

Full text of DOI:10.1080/00397919808004413

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Synthetic Communications:
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Synthetic Organic Chemistry
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An Easy and Efficient Method
for Cleavage of Carbon-
Nitrogen Double Bonds
Under Non-Aqueous and
Neutral Conditions
a
a
R. A. Hajipour & N. Mahboobkhah
a
College of Chemistry, Isfahan University of
Technology , Isfahan, Iran
Published online: 23 Aug 2006.
To cite this article: R. A. Hajipour & N. Mahboobkhah (1998) An Easy and
Efficient Method for Cleavage of Carbon-Nitrogen Double Bonds Under Non-
Aqueous and Neutral Conditions, Synthetic Communications: An International
Journal for Rapid Communication of Synthetic Organic Chemistry, 28:17,
3143-3149, DOI: 10.1080/00397919808004413
To link to this article: http://dx.doi.org/10.1080/00397919808004413
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