Canadian Journal of Chemistry p. 810 - 814 (2018)
Update date:2022-08-28
Topics:
Li, Yongshu
Xu, Nizhou
Mei, Guangyao
Zhao, Yun
Zhao, Yiyong
Lyu, Jinghui
Zhang, Guofu
Ding, Chengrong
A mild, simple process for the effective aerobic oxidative deoximation of a wide range of ketoximes and aldoximes has been developed that utilizes Fe(NO3)3·9H2O as the single catalyst and molecular oxygen as the green oxidant. The environmentally benign protocol provides moderate to excellent yield and broad functional groups tolerance and is a valuable synthetic method for practical applications. According the relevant verification experiment, a plausible mechanism has been proposed.
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