Journal of Organometallic Chemistry p. 297 - 306 (1990)
Update date:2022-08-11
Topics:
Jintoku, Tetsuro
Fujiwara, Yuzo
Kawata, Itaru
Kawauchi, Tomio
Taniguchi, Hiroshi
Various aromatic acids can be prepared from aromatic compounds and CO under mild conditions by Pd-based catalysts via direct aromatic C-H bond activation.With PdII catalysts, the reaction is electrophilic and proceeds with ortho-para orientation when an electron-donating group is attached to the benzene ring; addition of t-BuOOH and allyl halides makes the reaction catalytic with respect to palladium(II). β Naphthoic acid can be prepared from naphthalene and CO by the Pd/phenanthroline catalyst system in 421percent yield based on Pd and in 92percent selectivity.
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