Tetrahedron p. 15867 - 15876 (1997)
Update date:2022-08-16
Topics:
Palombi, Laura
Bonadiesa, Francesco
Scettri, Arrigo
Under microwave irradiation 3? molecular sieves promote the oxidation of secondary (linear and cyclic) and benzylic alcohols to the corresponding carbonyl compounds by t-butyl hydroperoxide. Under the same conditions, α,β-unsaturated alcohols are converted into α,β-epoxyalcohols in regio- and diastereoselective way. Both oxidative processes can be performed under solvent-free conditions; however, epoxidation of allylic alcohols is found to proceed with more satisfactory efficiency in saturated aliphatic hydrocarbon (n-hexane or cyclohexane).
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