Journal of Fluorine Chemistry p. 155 - 161 (1993)
Update date:2022-08-17
Topics:
Munavalli, S.
Rossman, D. I.
Rohrbaugh, D. K.
Ferguson, C. P.
The reaction of bis(trifluoromethyl) disulfide with organolithium reagents at -78 deg C results in simultaneous scission of both the C-S and S-S bonds.Under similar conditions, the alkyl and aryl disulfides undergo only S-S bond cleavage.This unusual behavior of bis(trifluoromethyl) disulfide is due to the presence of the trifluoromethyl function.The product distribution, the mechanism of bond fission and the mass spectral data of compounds thus formed are presented in this paper.
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